Why do leaves change colour in autumn?
Because the tree withdraws its most valuable resources before discarding the leaves — and the colours reveal what was there all along, plus something newly made.
The green is chlorophyll, the pigment that captures light for photosynthesis. It dominates all summer, masking everything else in the leaf.
Why the tree sheds leaves at all. Broadleaf leaves are thin and full of water, so they are destroyed by frost and lose water faster than frozen ground can supply it. In winter, a leaf costs more than it earns. Shedding is a controlled withdrawal, not a failure.
The sequence, triggered mainly by shortening day length rather than by temperature — which is why the timing is fairly consistent year to year:
Chlorophyll production stops and existing chlorophyll breaks down. Crucially, the tree reabsorbs the nitrogen and magnesium it contains — these are expensive nutrients, and recovering them is the point of the whole process.
Yellows and oranges are revealed. Carotenoids and xanthophylls were present all summer, doing accessory light capture and protecting against light damage. They simply become visible as the green goes. Birch, hazel and field maple are dominated by these.
Reds are newly made. Anthocyanins are synthesised during autumn, not revealed — which is why red colour varies enormously between years while yellow is consistent.
Why a tree would invest in making pigment in a leaf it is discarding is genuinely debated. Leading hypotheses: protecting the leaf from light damage while nutrients are withdrawn, since sunny cold days are exactly when the breakdown machinery is most vulnerable; and possibly deterring insects.
Best red displays follow warm sunny days and cool but frost-free nights, which favour sugar accumulation and anthocyanin production. A warm wet autumn gives dull colour; an early hard frost cuts it short.
Browns are tannins, what remains once everything else has gone.
Abscission finally seals and severs the leaf.