Why do recipes fail when you double them?
Because a recipe is a set of physical processes, not a list of proportions, and several of those processes do not scale linearly with quantity. Doubling the ingredients doubles the mass but does not double the pan, the surface area, or the rate at which heat moves.
The things that break:
Surface area to volume ratio falls. Double the volume in the same shaped vessel and the surface area grows by much less. Since evaporation, browning and heat transfer all happen at surfaces, everything that depends on a surface slows down relative to the bulk.
Evaporation reduction. A sauce reduced in half the time at single quantity takes far longer than twice as long doubled — which is why doubled stews come out watery if cooked to the original time.
Browning fails. Doubling meat in the same pan drops the pan temperature, releases more moisture than can evaporate, and the food steams instead of searing. The fix is batches, not a bigger burner.
Heat penetration is not linear. A cake twice as deep takes considerably more than twice as long for the centre to reach temperature, and the outside overcooks while waiting. Doubling a cake means two tins, not one deeper one — the single most common doubling failure.
Come-up and cool-down times lengthen, changing how long food spends at every intermediate temperature.
The ingredients that do not scale proportionally:
Salt and seasoning usually do scale, but should be adjusted at the end rather than doubled blindly.
Raising agents. Doubling baking powder in a larger, deeper item frequently produces over-rise then collapse.
Strong aromatics — garlic, chilli, spices, and particularly anything bitter — often need less than double.
Alcohol and acid concentrate differently depending on evaporation.
Thickeners behave non-linearly and are best added to effect.
Yeast need not be doubled; time can do the work.
What to do instead: keep vessel depth similar and increase area, cook in batches where browning matters, judge by state rather than time, and scale seasoning last.