What makes milk froth properly?
Protein, not fat — milk proteins unfold at the air-liquid interface and stabilise the bubbles, which is why skimmed milk actually froths more easily than whole, contrary to expectation.
The mechanism. Steam or agitation forces air into the milk. Proteins — principally casein and whey proteins — migrate to the surface of each bubble, unfold, and link together to form a film that stops the bubble collapsing. Fat interferes with this film, so higher fat means less volume — but produces a smoother, more stable, better-tasting foam with finer bubbles.
That trade-off explains the practical advice: whole milk for texture and flavour, semi-skimmed as a good compromise, skimmed for maximum volume and a drier, stiffer foam.
Temperature is the critical variable. Frothing works best starting cold, and the milk should not exceed roughly 65–70°C. Above that, proteins denature excessively, the foam collapses, and the milk develops a cooked, sulphurous flavour. Milk scalded once cannot be re-frothed properly, because the proteins have already changed.
The technique for steam wands: introduce air only at the start, with the tip just below the surface producing a gentle hissing — this is stretching. Then submerge the tip slightly and create a whirlpool to break large bubbles into fine ones and incorporate them — texturing. The result should be glossy and pourable, like wet paint, not stiff and bubbly.
Why plant milks behave differently. They contain different proteins, or very few, so many do not froth at all. Barista versions add proteins, stabilisers and adjust fat and acidity specifically to froth and to resist curdling in coffee. Soya froths relatively well; oat has become popular for texture and sweetness; almond and rice are hardest.
Why plant milk curdles in coffee: coffee is acidic, and acid plus heat destabilises the proteins. Warming the milk, adding coffee to milk rather than the reverse, and using a less acidic coffee all help.
Clean the wand immediately — dried milk is difficult to remove and a hygiene problem.