What does pH actually measure?
pH measures the concentration of hydrogen ions in a solution, on a logarithmic scale — and both parts of that matter for interpreting the number correctly.
The definition. pH is the negative logarithm (base 10) of the hydrogen ion concentration in moles per litre. The negative sign exists so that acidic solutions, which have high hydrogen ion concentrations, get low numbers.
Why the scale is logarithmic, and what that implies. Each whole number represents a tenfold change. pH 4 is ten times more acidic than pH 5, and a hundred times more acidic than pH 6. This is the most frequently missed point, and it makes small-sounding pH shifts substantial: ocean acidification of a few tenths of a unit represents a large proportional change in hydrogen ion concentration.
The scale in practice. Pure water at 25°C sits at 7 and is neutral — not because 7 is a magic number, but because water self-ionises slightly and, at that temperature, produces equal and specific concentrations of hydrogen and hydroxide ions. Below 7 is acidic; above 7 is alkaline (basic).
The scale is not capped at 0 and 14. Those are conventional limits reflecting common solutions. Concentrated acids can have negative pH and concentrated alkalis can exceed 14.
Neutral is temperature-dependent. Because self-ionisation increases with temperature, pure water at higher temperatures has a neutral pH below 7 — while remaining genuinely neutral, since the two ion concentrations are still equal.
Common misconceptions:
pH does not measure strength of an acid, it measures the resulting concentration. A dilute strong acid can have a higher pH than a concentrated weak one.
Alkaline diets and "alkaline water" rest on a misunderstanding: blood pH is tightly regulated within a narrow range by buffering systems, and what you drink does not move it. Stomach acid is strongly acidic by design, and anything swallowed encounters that first.
Buffers resist pH change, which is why biological systems stay stable.