Question

How do lithium-ion batteries actually degrade?

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Answer

Through two separate processes running simultaneously: calendar ageing, which happens regardless of use, and cycle ageing, which depends on how you charge and discharge. Understanding that both are running explains why advice about battery care is often contradictory.

What is physically happening:

Solid electrolyte interphase growth. A protective layer forms on the anode and thickens over time, consuming lithium and increasing internal resistance. This is the main driver of calendar ageing, and it continues in a drawer.

Lithium plating, where lithium deposits as metal rather than intercalating properly — accelerated by charging at low temperatures and at high rates, and effectively irreversible.

Electrode mechanical stress, as materials expand and contract with each cycle, cracking over time.

Electrolyte decomposition, accelerated sharply by heat.

What actually accelerates degradation, in order of importance:

Heat. By a wide margin the worst factor. Chemical degradation roughly doubles in rate for each 10°C increase — a phone left in a hot car or a laptop running hot under load loses capacity far faster than one that stays cool.

Time at high state of charge. Sitting at 100% keeps the cell at high voltage, which stresses it continuously. This is why charge limiting features exist and why manufacturers added optimised charging.

Deep discharges to very low levels.

High charge and discharge rates, though modern thermal management mitigates much of this.

What genuinely helps:

Keep it cool. Remove thick cases while fast charging, avoid direct sun, and do not charge a hot device.

Stay in the middle of the range where practical — roughly 20–80% is materially gentler than 0–100%, and charge limiting to 80% is worth using on devices that support it.

Store at around 50%, in a cool place, if a device is unused for months. Storing full or empty is what damages long-term storage.

Use fast charging when you need it, not by default.

What does not matter: partial charging causes no harm — the memory effect belonged to older chemistries — and overnight charging is managed by the charging circuit, not by the cell.

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